43.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 19.10.2016 *
Version number 13
Revision: 19.10.2016
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: INDU-PRIMER-S (B.Komp.)(Primer-2000 S (B-Komp.)) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Primer · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS02 flame Flam. Liq. 2 H225 Highly flammable liquid and vapour. GHS05 corrosion Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. GHS07 Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H336 May cause drowsiness or dizziness. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS02, GHS05, GHS07 · Signal word Danger · Hazard-determining components of labelling: Ethylenediamine ethyl acetate 2,4,6-tris(dimethylaminomethyl)phenol ethylenediamine (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 19.10.2016
Trade name: INDU-PRIMER-S (B.Komp.)(Primer-2000 S (B-Komp.)) (Contd. of page 1)
· Hazard statements H225 Highly flammable liquid and vapour. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H336 May cause drowsiness or dizziness. · Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Mixture consisting of the following components. · Dangerous components: CAS: 141-78-6 ethyl acetate EINECS: 205-500-4 Flam. Liq. 2, H225; CAS: 25707-70-4 Ethylenediamine EINECS: 247-196-6 Skin Corr. 1B, H314;
50-100% Eye Irrit. 2, H319; STOT SE 3, H336 10-25% Acute Tox. 4, H312; Skin Sens. 1, H317
CAS: 90-72-2 2,4,6-tris(dimethylaminomethyl)phenol EINECS: 202-013-9 Skin Corr. 1B, H314; Skin Sens. 1, H317; Aquatic Chronic 3, H412
10-25%
CAS: 108-10-1 4-methylpentan-2-one EINECS: 203-550-1 Flam. Liq. 2, H225; SE 3, H335
< 2.5% Acute Tox. 4, H332; Eye Irrit. 2, H319; STOT
CAS: 107-15-3 ethylenediamine < 0.5% EINECS: 203-468-6 Flam. Liq. 3, H226; Resp. Sens. 1, H334; Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317 · Additional information For the wording of the listed hazard phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. (Contd. on page 3) GB
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Trade name: INDU-PRIMER-S (B.Komp.)(Primer-2000 S (B-Komp.)) (Contd. of page 2)
· After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Don't cause vomiting Show the pack or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increaseing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Store in cool, dry place in tightly closed containers. Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Keep away from children. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store in cool location. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Store in cool, dry conditions in well sealed containers. (Contd. on page 4) GB
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Trade name: INDU-PRIMER-S (B.Komp.)(Primer-2000 S (B-Komp.)) (Contd. of page 3)
Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 141-78-6 ethyl acetate (50-100%) WEL Short-term value: 400 ppm Long-term value: 200 ppm 108-10-1 4-methylpentan-2-one (< 2.5%) WEL Short-term value: 416 mg/m³, 100 ppm Long-term value: 208 mg/m³, 50 ppm Sk, BMGV · Ingredients with biological limit values: 108-10-1 4-methylpentan-2-one (< 2.5%) BMGV 20 µmol/L Medium: urine Sampling time: post shift Parameter: 4-methylpentan-2-one · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing.
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Fluid Colour: Light yellow · Smell: Amine-like (Contd. on page 5) GB
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Trade name: INDU-PRIMER-S (B.Komp.)(Primer-2000 S (B-Komp.)) (Contd. of page 4)
· Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: 77 °C · Flash point:
-4 °C
· Ignition temperature:
460 °C 460 °C
· Self-inflammability:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive. However, formation of explosive air/ steam mixtures is possible.
· Critical values for explosion: Lower: 2.1 Vol % Upper: 11.5 Vol % · Steam pressure at 20 °C:
97 hPa
· Density at 20 °C
0.91 g/cm³
· Solubility in / Miscibility with Water: Not miscible or difficult to mix · Viscosity: dynamic at 20 °C: · 9.2 Other information
10 mPas No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Decomposes with water, acids and alkalis · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 141-78-6 ethyl acetate Oral LD50 5600 mg/kg (rats) >18000 mg/kg (rbt) Inhalative LC50/4 h 1600 mg/l (rats) 108-10-1 4-methylpentan-2-one Oral LD50 2100 mg/kg (rats) Dermal LD50 16000 mg/kg (rabbit) Inhalative LC50/4 h 8.3-16.6 mg/l (rats) (Contd. on page 6) GB
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Trade name: INDU-PRIMER-S (B.Komp.)(Primer-2000 S (B-Komp.)) (Contd. of page 5)
107-15-3 ethylenediamine Oral LD50 500 mg/kg (rats) Dermal LD50 730 mg/kg (rbt) Inhalative LC50/4 h 0.3 mg/l (mus) · Primary irritant effect: · Skin corrosion/irritation Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation May cause an allergic skin reaction. · Additional toxicological information: Sensitizing · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure May cause drowsiness or dizziness. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS 08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products) 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous substances · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. GB
(Contd. on page 7)
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Trade name: INDU-PRIMER-S (B.Komp.)(Primer-2000 S (B-Komp.)) (Contd. of page 6)
SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR · IMDG, IATA
UN2924 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. (ETHYL ACETATE) FLAMMABLE LIQUID, CORROSIVE, N.O.S. (ETHYL ACETATE)
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
3 Flammable liquids. 3+8
· 14.4 Packing group · ADR, IMDG, IATA
II
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user · Kemler Number: · EMS Number:
Warning: Flammable liquids. 33 F-E,S-C
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Transport category · Tunnel restriction code · UN "Model Regulation":
1L 2 D/E UN2924, FLAMMABLE LIQUID, CORROSIVE, N.O.S. (ETHYL ACETATE), 3 (8), II
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 · National regulations · Technical instructions (air): · Class Share in % · NK 71.3 · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. The classification based on german instructions. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. GB
(Contd. on page 8)
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Trade name: INDU-PRIMER-S (B.Komp.)(Primer-2000 S (B-Komp.)) (Contd. of page 7)
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H412 Harmful to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Flam. Liq. 2: Flammable liquids – Category 2 Flam. Liq. 3: Flammable liquids – Category 3 Acute Tox. 4: Acute toxicity – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Resp. Sens. 1: Respiratory sensitisation – Category 1 Skin Sens. 1: Skin sensitisation – Category 1 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB